Date of Award

May 2014

Degree Type

Dissertation

Degree Name

Doctor of Philosophy

Department

Physics

First Advisor

Paul F. Lyman

Committee Members

Daniel F. Agterberg, Marija Gajdardziska-Josifovska, Dilano K. Saldin, Michael Weinert

Keywords

Polar Oxide, Surface Science, Surface X-ray Diffraction

Abstract

An atomic scale study of surface/interface structure is required to properly understand physical and chemical phenomena such as crystal growth, lubrication and electrochemistry. The stability of polar oxide surface has long been an interesting question. A bulk-terminated polar oxide surface comprises alternating layers of opposite charges, thus resulting in diverging surface energies. In order to reduce the surface energy, various reconstruction-stabilized MgO (111) surfaces have been reported

experimentally. However, the atomic structure of the MgO (111)rt3×rt3R30o<\super> reconstructed surface remains unclear.

Using a third-generation X-ray source is one of the feasible methodologies to probe such a system due to its increase of sensitivity on the interface layer. Surface X-ray diraction (SXRD) experiments were performed for the MgO(111) rt3×rt3R30o<\super> reconstructed surface at Advanced Photon Source, Argonne National Laboratory. The sample surface was prepared at home laboratory by annealing in a tube furnace for 36hrs at 1050o<\super>C, with N2<\sub> blowing at rate 1 to 2 scft. Crystal truncation rod (CTR) and super structure rod (SSR) measurements were acquired in both the absence and presence of a thin layer of water, obtained by compressing the bulk water layer with a thin Kapton sheet.

A differential evolution algorithm, GenX, was used to search for the appropriate atomic model of reconstructed structure. Some reasonable models are presented and discussed with quantitative calculation of optimizing parameters (R factor and chi square). Preliminary SXRD results of the dry surface and solid-liquid interface are compared. This determination will shed light on whether physical (as opposed to chemical) factors are operant in the formation of ice-like layers.

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